mean chi-2 = -3.845215e-05 variance chi-2 = 19.49047 std.dev. chi-2 = 4.414802 Parvseval's theorem - size signal vector invariant to change basis var(yout184) = sum(yout184^2)/16384 = sum(Mod(a)^2)) = C(0) = 19.48929 first 20 values of C(t); note C(0) = variance [1] 19.489285 18.009616 15.247437 13.633616 13.706762 14.740587 16.006862 [8] 16.270025 14.439963 11.713520 10.733692 12.100012 13.886611 14.502295 [15] 13.789323 11.949852 9.803482 9.191256 10.793810 12.592394 summary of fit to C(t) Formula: Ct ~ C * exp(-time/tau) * (cos(sqrt(XX/C - 1/tau^2) * time) + 1/(tau * sqrt(XX/C - 1/tau^2)) * sin(sqrt(XX/C - 1/tau^2) * time)) Parameters: Estimate Std. Error t value Pr(>|t|) tau 0.185765 0.006422 28.92 <2e-16 *** C 12.316130 0.184796 66.65 <2e-16 *** --- Signif. codes: 0 `***' 0.001 `**' 0.01 `*' 0.05 `.' 0.1 ` ' 1 Residual standard error: 1.664 on 498 degrees of freedom Correlation of Parameter Estimates: tau C 0.2501 torsional spring constant, from fit value C(0): K = 52.77597 Kcal/mol freq. of torsional oscillation, from K: w0 = 16.93435 ps^-1 freq. of Brownian model oscillation, from C & tau: w1 = 16.05596 ps^-1